Simultaneous correlation of liquid-liquid equilibria for ternary systems and phase equilibria for constituent binary systems by modified new activity coefficient model

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چکیده

A concentration-dependent surface area parameter model (Iwai, Fluid Phase Equilibria, 465 (2018) 24–32) was modified to avoid the restriction conditions for parameters of pure components. The is applied correlate ternary liquid-liquid equilibria and constituent binary phase with one set parameters. correlated results both vapor-liquid obtained by are better than those NRTL UNIQUAC models. simultaneously represents experimental data at multiple temperatures

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ژورنال

عنوان ژورنال: Fluid Phase Equilibria

سال: 2022

ISSN: ['0378-3812', '1879-0224']

DOI: https://doi.org/10.1016/j.fluid.2022.113411